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Book synopsis

Self-assembly based on range of non-covalent§interactions is a recent tool in the chemistry§tool-kit. An important factor in the process of§assembling are the complementary binding motifs on§the components and these could be simple organic§molecules to metals to complex amino acids. Recent§years have witnessed a few breakthroughs in the field§of catalyst designing via self-assembly, but there is§immense need of new approaches.§ This book outlines strategies to prepare metal§complexes with chelating, template-centered§bis-phosphine ligands by self-assembly of simple hard§and soft metal complex precursors with bi-functional§phosphine-catecholate ligands in a single synthetic§step. The choice of template of different size and§coordination number permits to adjust the bite angle§of the chelating bis-phosphine unit in a predictable§manner. Chirality in chelate complexes has been§demonstrated in simple and excellent manner.§ This book aims at an audience of advanced students,§experts and scientists working in catalysis via§self-assembly, bimetallic complexes, hard-soft§acid-base complexes and ligand designing.

Book details

Book category Books in English Mathematics & science Chemistry

• Full title: Catechol Phosphines
• Author: Samir Chikkali
• Language: English
• Binding: Paperback
• Number of pages: 200
• EAN: 9783639071382
• ISBN: 3639071387
• ID: 04334031
• Publisher: VDM Verlag Dr. Mueller E.K.
• Weight: 272 g
• Dimensions: 229 × 152 × 11 mm
• Date of publishing: 03. September 2008

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