Code: 02183035

Correlation and Localization

Name: Correlation and Localization
Brand: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
SKU: 02183035
Price: 215.83 EUR
Availability: InStock
Author: Peter R. Surjan
ISBN: 9783662156254

by Peter R. Surjan

Language: English
Binding: Paperback
Number of pages: 236
Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, 2013
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Book synopsis

This volume contains review and research articles in a field of quantum chemical methodology: the theory of electron correlation and the localization problem. Correlation energy (i.e., the energy beyond the Hartree-Fock) plays an important role in the theoretical description of several chemical processes (reactions, excitations, ionization) while localization in quantum chemistry usually emerges as a mathematical transformation of the wave function. The connection between these two issues is provided by the need to evaluate correlation energy for larger molecules, which is much easier in terms of localized contributions. The articles selected discuss copuled cluster, perturbational and geminal-based schemes, and cover wave function as well as density based approaches.