Code: 06813412

Neue Ein-Topf-Sequenzen

Name: Neue Ein-Topf-Sequenzen
Brand: VDM Verlag Dr. Müller
SKU: 06813412
Price: 79.90 EUR
Availability: BackOrder
Author: Christoph J. Kressierer
ISBN: 9783639037630

by Christoph J. Kressierer

Language: German
Binding: Paperback
Number of pages: 456
Publisher: VDM Verlag Dr. Müller, 2008
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Book synopsis

In palladium- und rhodiumkatalysierten Alder-En-analogen Reaktionen wurden In-Allylalkohol-Substrate cycloisomerisiert, die dann in einer anschließenden Tautomerie zu den entsprechenden Enalen umlagerten. Daneben wurden in Heck-Carbopalladierungsreaktionen ebenfalls In-Allylalkohole eingesetzt, die in einer Folge aus Carbopalladierung, Heck-Reaktion und anschließender Tautomerie ebenfalls Enale bildeten. Diese so gebildeten Enale wurden als Diversitätsmodule benutzt, um Konsekutivreaktionen im Ein-Topf-Verfahren anzuschließen. Hier konnte eine Reihe von Konsekutivreaktionen durchgeführt werden, darunter Wittig-Olefinierungen, reduktive Aminierungen und Knoevenagel-Kondensationen, die die Diversität und Komplexität der Reaktionsprodukte enorm erhöhten.

Book details

Book category Books in German Naturwissenschaften, Medizin, Informatik, Technik Chemie Organische Chemie

79.90 €

Full title: Neue Ein-Topf-Sequenzen
Subtitle: Auf der Basis cyclisierender Isomerisierungen von In-Allylalkoholen
Author: Christoph J. Kressierer
Language: German
Binding: Paperback
Number of pages: 456
EAN: 9783639037630
ID: 06813412
Publisher: VDM Verlag Dr. Müller
Weight: 602 g
Dimensions: 220 × 154 × 30 mm
Published: 2008