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Book synopsis

Na osnovanii provedennykh neempiricheskikh kvantovo-khimicheskikh raschetov v ramkakh predlozhennoy model'noy skhemy izucheny mezhchastichnye vzaimodeystviya v rasplavakh vol'framatov shchelochnykh i shchelochnozemel'nykh metallov s privlecheniem opredelyayushchikh faktorov vliyaniya: kislotno-osnovnykh svoystv rasplava, poverkhnosti elektroda i elektricheskogo polya. Na osnovanii poluchennykh rezul'tatov obosnovan kislotno-osnovnyy mekhanizm formirovaniya elektrokhimicheski aktivnykh kompleksov (EAK), svodyashchiysya k prioritetnomu obrazovaniyu kationizirovannykh chastits, kolichestvo i tip kotorykh opredelyaetsya udel'nym zaryadom i kontsentratsiey kationov, chto podtverzhdaet fundamental'nyy printsip kationnogo kataliza. Pri izuchenii napravlennosti protsessov elektrovosstanovleniya chastits vol'framatsoderzhashchikh rasplavov obnaruzhen prioritet odnovremenogo perenosa elektronov dlya vsekh kationizirovannykh form EAK, po sravneniyu s posledovatel'nym, vyzvannyy vneshnesfernoy kationizatsiey vol'framat-aniona. Obnaruzheno, chto pri posledovatel'nom perenose elektronov v reaktsiyakh vosstanovleniya EAK, v otlichie ot odnovremennogo, proiskhodit izmenenie dentatnosti kationov vneshney obolochki EAK.

Book details

• Full title: Vol'framatsoderzhashchie Solevye Rasplavy
• Author: Veniamin Solov'ev, Lyudmila Chernenko
• Language: Russian
• Binding: Paperback
• Number of pages: 184
• EAN: 9783659986598
• ISBN: 3659986593
• ID: 07092686
• Publisher: Palmarium Academic Publishing
• Weight: 277 g
• Dimensions: 229 × 152 × 11 mm
• Date of publishing: 18. July 2013

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