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Book synopsis

V rabote predstavleny jexperimental'no poluchennye konstanty ustojchivosti komplexov serebra(I) s glicinat-ionom v vodnyh rastvorah jetanola, izopropanola, dimetilsul'foxida i acetona, a takzhe jental'pii reakcij obrazovaniya jetih komplexov v vodno-jetanol'nyh i vodno-dimetilsul'foxidnyh rastvoritelyah. Opredeleny teplovye jeffekty reakcii protonirovaniya glicinat-iona v smesyah voda-jetanol i voda-dimetilsul'foxid i izmenenie jenergii Gibbsa peresol'vatacii glicinat-iona v vodno-dimetilsul'foxidnyh rastvoritelyah. Pokazano, chto v reakciyah komplexoobrazovaniya Ag(I) s glicinat-ionom sobljudajutsya osnovnye zakonomernosti v izmenenii termodinamicheskih harakteristik reakcii i sol'vatacii reagentov, ustanovlennye dlya ionov drugih d-metallov, chto pozvolyaet prognozirovat' izmenenie ustojchivosti glicinatnyh komplexov Ag(I) i jental'pii reakcij ih obrazovaniya pri zamene vody na organicheskie rastvoriteli. Rezul'taty, poluchennye v rabote, imejut fundamental'nyj harakter i mogut ispol'zovat'sya kak spravochnye velichiny dlya provedeniya raschetov ravnovesnyh processov v rastvorah aminokislot, a takzhe v uchebnyh i nauchnyh celyah studentami i aspirantami, izuchajushhimi koordinacionnuju i fizicheskuju himiju rastvorov.

Book details

• Full title: Komplexoobrazovanie glicinat-iona s Ag(I) v vodno-organicheskih smesyah
• Author: Vera Isaeva, Valentin Sharnin, Zhenni Gesse
• Language: Russian
• Binding: Paperback
• Number of pages: 76
• EAN: 9783659776113
• ID: 09881326
• Publisher: LAP Lambert Academic Publishing
• Weight: 130 g
• Dimensions: 220 × 150 × 5 mm
• Date of publishing: 19. September 2015

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