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Book synopsis

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Br

Book details

Book category Knihy po anglicky Mathematics & science Chemistry Organic chemistry

• Full title: Organic Reactions V73 Carbonyl Allylboration
• Author: Dennis G. Hall, Roger Adams, Leo A. Paquette
• Language: English
• Binding: Paperback
• Number of pages: 596
• EAN: 9781118344453
• ISBN: 1118344456
• ID: 01401885
• Publisher: John Wiley & Sons Inc
• Weight: 878 g
• Dimensions: 228 × 157 × 31 mm
• Date of publishing: 01. December 2012

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