Theoretical study on graphite and lithium metal as anode materials for next-generation rechargeable batteries / Najlacnejšie knihy
Theoretical study on graphite and lithium metal as anode materials for next-generation rechargeable batteries

Kód: 22492132

Theoretical study on graphite and lithium metal as anode materials for next-generation rechargeable batteries

Autor Gabin Yoon

This thesis describes in-depth theoretical efforts to understand the reaction mechanism of graphite and lithium metal as anodes for next-generation rechargeable batteries. The first part deals with Na intercalation chemistry in gr ... celý popis

247.66


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Viac informácií o knihe Theoretical study on graphite and lithium metal as anode materials for next-generation rechargeable batteries

Nákupom získate 623 bodov

Anotácia knihy

This thesis describes in-depth theoretical efforts to understand the reaction mechanism of graphite and lithium metal as anodes for next-generation rechargeable batteries. The first part deals with Na intercalation chemistry in graphite, whose understanding is crucial for utilizing graphite as an anode for Na-ion batteries. The author demonstrates that Na ion intercalation in graphite is thermodynamically unstable because of the unfavorable Na-graphene interaction. To address this issue, the inclusion of screening moieties, such as solvents, is suggested and proven to enable reversible Na-solvent cointercalation in graphite. Furthermore, the author provides the correlation between the intercalation behavior and the properties of solvents, suggesting a general strategy to tailor the electrochemical intercalation chemistry. The second part addresses the Li dendrite growth issue, which is preventing practical application of Li metal anodes. A continuum mechanics study considering various experimental conditions reveals the origins of irregular growth of Li metal. The findings provide crucial clues for developing effective counter strategies to control the Li metal growth, which will advance the application of high-energy-density Li metal anodes.

Parametre knihy

Zaradenie knihy Knihy po anglicky Mathematics & science Chemistry Physical chemistry

247.66

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